I am surprised that there have been no updates to the webmin interface to support the new samba version (that has been rolled out to most major linux distros now) -- am I the only one that has been using webmin to do my admin on samba servers ? I think NOT...
Anyway - here is a quick and dirty fix to the start/stop entries in the webmin samba module to correct it for Version 4:
Command to stop Samba servers
service smbd stop && service nmbd stop
Command to start Samba servers
service smbd start && service nmbd start